Resultados de investigación

Full experimental details for the synthesis, characterization, and crystallographic data (PDF). Coordinates (XYZ)., Peer reviewed

1. 1H and 13C{1H} spectra and crystal structure data for the complexes 1–4 and 6: S2 2. Crystal structure determination of complexes 1-4 and 6: S7, Peer reviewed

15 pages. -- Figure S1. Sediment and depth data for each sampling station (station ID numbers correspond to Table S1). -- Figure S2. Relationships between oxygen and total faunal biomass and abundance collected using the box core (a, c) and dredge (b, d) for all sampling stations with oxygen concentrations above 3 ml l–1. -- Figure S3. Vertical abundance distribution of species in the sediment (showing the sum of all individuals across all stations). -- Figure S4. Vertical biomass (gram wet weight) distribution of species in the sediment (showing total biomass across all stations).-- Figure S5. Boxplot of oxygen concentrations for each seasonal quarter based on all data points in Fig. 3a, indicating lower median oxygen concentrations in quarter 3 and 4. -- Figure S6. Simulated daily oxygen concentrations for each sampling station. S describes the day of sampling. -- Figure S7. Comparison of time series of near-bed oxygen concentrations with model simulations at the same location from 2013 to 2018. -- Figure S8. Relationship between annual trawling intensities at Station 9 and the minimum, average and maximum yearly near-bed oxygen concentration (as measured 3.7 km from Station 9, see Fig. 1 and 3). -- Table S1. Overview of environmental conditions. -- Table S2. Wet weight (WW) to shell-free wet weight (SFWW) conversions for bivalve species. -- Table S3. Length-weight relationships for all species identified in the box corer. -- Table S4. PerMANOVA analyses based on Bray-Curtis dissimilarities using longevity biomass data. Table S5. PerMANOVA analyses based on Bray-Curtis dissimilarities using biomass (a) and abundance (b) data in four vertical sediment sections (0–2, 2–4, 4–8 and >8 cm) in relation to changes in oxygen concentrations and trawling intensity. -- Supplementary Text S1: Information on longevity of Astarte elliptica. -- Supplementary Text S2: Calculation of benthic impact from fishing., Peer reviewed

1H and 13C NMR spectra of the organometallic compounds and N-methylated amines, catalyst screening and optimization, isotopic labeling experiments, and DFT-optimized structures (PDF). Coordinates (XYZ)., Peer reviewed

The supporting information: Figures S1–S26: NMR spectra of the complexes; Figure S27: UV–Vis spectra of the complexes; Figure S28: Measurement of the intracellular levels of ROS., Peer reviewed

NMR spectra of functionalized imidazolium salts and copper(I) compounds; isolation procedure, characterization, and NMR spectra of 1,4-substituted-1,2,3-triazole derivatives, and DFT energy data (PDF). Optimized coordinates for catalytic intermediates and transition states (XYZ)., Peer reviewed

General experimental methods and instrumentation, general procedure for the synthesis of thioureas 1a–q, general procedure for the synthesis of 1,3-thiazines 2a′–p′ and 2r′, synthesis of catalyst [Au(NCMe)(CyJohnPhos)]SbF6 (IC), and 1H, 13C{1H}-APT, COSY, HSQC, and HMBC NMR spectra., Peer reviewed

Peer reviewed

Information about general procedures and materials; X-ray structure determinations (CCDC 2160386–2160389); crystallographic data; DFT and electrochemistry methods; and multinuclear and NMR spectra and CV for characterization and mechanism’s determination and selected bond angles and lengths in the X-ray structures of 2a, 2b, 3a′, and 5a., Peer reviewed

Peer reviewed