BUSCADOR RECOLECTA

2. CanVilaCatchment_Rainfall-5min_2017-2021.xlsx The precipitation data (mm) in the Can Vila Catchment (5min time step) for the period 2017-2021, Peer reviewed

3. CanVilaCatchment_Runoff-5min_2017-2021.xlsx The runoff data (mm) in the 0.60 km2 Can Vila Catchment (5min time step) for the period 2017-2021, Peer reviewed

4. CanVilaCatchment_SWC-B2-5min_2017-2021.xlsx The Soil Water Content data (cm3.cm-3) in the Can Vila Catchment (5min time step) for the period 2017-2021. SWC data are. Mean values from 0-30, 30-60 and 60-90cm depth, Peer reviewed

Lápida situada a los pies del altar de la Piedad. La inscripción está en dos partes, en el extremo superior sobre la cabeza de la estatua yacente del tesorero, y a sus pies. El extremo derecho de la línea de los pies está cortado por el muro, por lo cual es ilegible al final, aunque se puede restituir. Se puede identificar al personaje enterrado en este sepulcro con Gómez Carrillo de Albornoz, citado en la inscripción del arco en el altar. La inscripción ha sido publicada por A. Sanz Serrano, La Catedral de Cuenca, Cuenca (1959), 136 y J. Bermejo, La Catedral de Cuenca, Cuenca (1977), 210., CSIC. Proyecto intramural: “Epigrafía latina inédita de los siglos XV al XVIII en monumentos civiles y eclesiásticos de la provincia de Cuenca (2006-2007). Referencia: 2006 | 0| 011., Peer reviewed

Lápida en el centro del pavimento de la Capilla de los Caballeros, próxima a la pila bautismal. Texto grabado en la piedra, enmarcado por una línea simple., CSIC. Proyecto intramural: “Epigrafía latina inédita de los siglos XV al XVIII en monumentos civiles y eclesiásticos de la provincia de Cuenca (2006-2007). Referencia: 2006 | 0| 011., Peer reviewed

32 pages. -- Experimental details. -- Computational details. -- Calculating binding energies. -- Calculating ORR activity, Electrolyte effects play an important role in the activity of the oxygen reduction reaction (ORR) of Pt-based electrodes. Herein, we combine a computational model and rotating disk electrode measurements to investigate the effects from phosphate anion poisoning for the ORR on well-defined extended Pt surfaces. We construct a model including the poisoning effect from phosphate species on Pt(111) and Cu/Pt(111) based on density functional theory simulations. By varying the subsurface Cu content of the Cu/Pt(111) alloy, we tune the *OH binding energies on the surface by means of ligand effects, and as a result, we tune the ORR activity. We have investigated the effect of adsorbed phosphate species at low overpotentials when tuning *OH binding energies. Our results display a direct scaling relationship between adsorbed *OH and phosphate species. From the model, we observe how the three-fold binding sites of phosphate anions limit the packing of poisoning phosphate on the surface, thus allowing for *OH adsorption even when poisoned. Our work shows that, regardless of surface site blockage from phosphate, the trend in the catalytic oxygen reduction activity is predominantly governed by the *OH binding., Peer reviewed

14 pages. -- PDF includes: 1 Methods. -- 1.1 Synthesis of the molecular precursors. -- 1.2 Sample preparation and on-surface synthesis. -- 1.3 Experimental details on the imaging method. -- 1.4 Ab-initio Calculations and quantum electron transport simulations. -- 2 Analysis of interpolymer distance. -- 3 Electronic properties of Ph-7-13-AGNR. -- 4 Surface-induced planarization of the peripheral phenyl ring in isolated ribbons., Recent advances on surface-assisted synthesis have demonstrated that arrays of nanometer wide graphene nanoribbons can be laterally coupled with atomic precision to give rise to a highly anisotropic nanoporous graphene structure. Electronically, this graphene nanoarchitecture can be conceived as a set of weakly coupled semiconducting 1D nanochannels with electron propagation characterized by substantial interchannel quantum interferences. Here, we report the synthesis of a new nanoporous graphene structure where the interribbon electronic coupling can be controlled by the different degrees of freedom provided by phenylene bridges that couple the conducting channels. This versatility arises from the multiplicity of phenylene cross-coupling configurations, which provides a robust chemical knob, and from the interphenyl twist angle that acts as a fine-tunable knob. The twist angle is significantly altered by the interaction with the substrate, as confirmed by a combined bond-resolved scanning tunneling microscopy (STM) and ab initio analysis, and should accordingly be addressable by other external stimuli. Electron propagation simulations demonstrate the capability of either switching on/off or modulating the interribbon coupling by the corresponding use of the chemical or the conformational knob. Molecular bridges therefore emerge as efficient tools to engineer quantum transport and anisotropy in carbon-based 2D nanoarchitectures., Peer reviewed

17 pages. -- 1. Experimental Section. -- 2. Supplementary Table S1-S2 and Figs. S1-S17. -- 3. References, Peer reviewed

38 pages. -- 1. Thermal Properties. -- 2. Cyclic Voltammetry. -- 3. Optical Characterization. -- 4. Energy Level Diagram. -- 5. Self-Assembly. -- 6. Water Contact Angle Measurements. -- 7. XPS Measurements. -- 8. Perovskite Solar Cells. -- 9. Surface Recombination Velocity Measurements. -- 10. Drift-Diffusion Simulations. -- 11. Shelf-Life Stability. -- 12. Synthesis. -- 12.1. Naphthalene monoimides 2a-2d. -- 12.2. Naphthalene diimides 3a-3d. -- 13. References, Electron-transport-layer-free (ETL-free) perovskite solar cells (PSCs) show great promise for commercialization due to their simple design and ease of fabrication. However, the interface between the transparent conductive oxides such as indium-doped tin oxide (ITO) and the perovskite is not optimal due to differences in their work functions, surface defects, and wettability of the substrates. Surface modification of ITO through self-assembled monolayers (SAMs) to get ITO/SAM charge selective layers has shown great improvement in device performance in recent years, but little emphasis has been put on the stability of these devices. Here, we address this gap by introducing a series of newly synthesized naphthalene-imide derivatives which self-assemble at the interface between ITO and the perovskite interface and study their impact on the thermal stability of triple-cation PSCs. The chemical and thermal stabilities of the naphthalene-imide SAMs help improve the thermal stability of the devices, reaching T80 lifetimes exceeding 800 h for devices containing a pyridine-functionalized naphthalene diimide carboxylic acid at 85 °C in air. In addition, all SAMs improve the stabilized power output of the devices with respect to ITO-only reference devices. Drift-diffusion simulations reveal the strong influence of the ITO work function on the efficiency in ETL-free devices, and a work function reduction of 0.2 eV could improve efficiencies by over 30%. The functional diversity of naphthalene imides coupled with the ease of SAM deposition opens a pathway for stable, high-performing PSCs based on electron selective monolayers., Peer reviewed

(A) Alignment of amino acids (aa) sequences of the isoform B of Exp (aa 356–433) and homologs; the blue square indicates 8 aa highly conserved, the red square includes 9 aa less conserved. (B-D) Show projections of confocal sections and (E-F) show single confocal sections. (B) The overexpression of expΔCM2 in an exp reb mutant background rescues the lack of extracellular chitin deposition. (C, D) The simultaneous expression of expΔCM2 and GFP-kkv produces morphogenetic defects in the trachea (arrowheads in C) and ectopic chitin deposition in the lumen of salivary glands (D). (E, F) Overexpressed Exp localises mainly in the apical region (orange arrowheads) with respect the basal domain (yellow arrowheads), while the apical accumulation of overexpressed ExpΔCM2 is less conspicuous (F). (G) Quantifications of accumulation of Exp and ExpΔCM2 in apical versus basal region. n corresponds to the number of ratios analysed (apical/basal ratio per cell), and brackets indicate the number of embryos used. Ratios were obtained from the apical (orange line in E) and basal (yellow line in E) domains of single cells in trachea and salivary glands. The underlying data for quantifications can be found in the S1 Data. Scale bars B, C: 25 μm; D-F: 10 μm., Peer reviewed