Resultados de investigación

22 pages. -- PDF file includes: Experimental Procedures; DFT calculations. -- Figure S1. (a,b) SEM image and EDX spectrum of Ni-MOF-1D sample. (c) High magnification STEM-HAADF image and EDX elemental mapping showing the elemental distribution in a Ni-MOF-1D sample. (d) XRD pattern of Ni-MOF-1D. -- Figure S2. High magnification HAADF-STEM images and detailed STEM-EDX elemental maps of a Ni-MOF 1D catalyst. -- Figure S3. iDPC-STEM images of Ni-MOF-1D with different magnifications. -- Figure S4. (a) XPS survey spectrum of Ni-MOF-1D. (b-d) High resolution XPS spectra of b) C 1s, c) N 1s, and d) Ni 2p. -- Table S1 Detailed EXAFS fitting model and parameters of Ni-MOF-1D. -- Figure S5. Wavelet transform (WT) analysis of (a) Ni-MOF-1D, (b) Ni foil, and (c) NiO. -- Figure S6. 1H NMR spectra of the obtained sample of Ni-MOF-1D. -- Figure S7. (a) Projected integral of the charge density in the non-periodic direction. (b) Projected integral of the charge density in the periodic direction of Ni-MOF-1D. -- Figure S8. Calculated electron localization function (ELF) of Ni-MOF-1D. -- Figure S9. (a) SEM-EDX compositional maps and (b) EDX spectra of S@Ni-MOF-1D. (c) XRD pattern of S@Ni-MOF-1D. (d) TGA profile from S@Ni-MOF-1D measured in N2 atmosphere. (e) N2 adsorption-desorption isotherms of Ni-MOF-1D and S@Ni-MOF-1D. Inset: Pore size distribution of Ni-MOF-1D and S@Ni-MOF-1D. -- Figure S10. Electrical conductivity of the two hosts tested before and after fusion with sulfur. -- Figure S11. Binding energies and adsorbed structures of LiPS on the surface of carbon calculated by DFT. -- Figure S12. Binding energies and adsorbed structures of LiPS on the surface of Ni-MOF-1D calculated by DFT. -- Figure S13. The optimized adsorption configuration of Li2S decomposition on carbon. -- Figure S14. The optimized adsorption configuration of Li2S decomposition on Ni-MOF-1D. -- Figure S15. (a) CV curve of Ni-MOF-1D as electrode measured in symmetric coin cell configuration using an electrolyte containing 1 mol L−1 LiTFSI dissolved in DOL/DME (v/v =1/1). (b) CV curves of symmetric cells from 1 to 50 cycles. (c) CV profiles of Ni-MOF-1D electrodes in symmetric cells at scan rate from 2 mV s-1 to 20 mV s-1. -- Figure S16. EIS spectra of symmetrical cells with different host materials, Ni-MOF-1D (a) and Super P (b), using an electrolyte containing 0.5 mol L-1 Li2S 6 and 1 mol L-1 LiTFSI dissolved in DOL/DME (v/v = 1/1). -- Figure S17. Onset potential for Li–S redox reactions. -- Figure S18. CV curves of S@Super P at different scan rates. -- Figure S19. First four cycles of CV curves of (a) S@Ni-MOF-1D, and (b) S@Super P performed at a scan rate of 0.1 mV s−1. -- Figure S20. Plots of CV peak current. -- Figure S21. Charge profiles of S@Ni-MOF-1D, and S@Super P electrodes showing the overpotentials for conversion between soluble LiPS and insoluble Li2S2/Li2S. --Figure S22. (a) Galvanostatic charge/discharge profiles of S@Super P electrodes at different current densities range from 0.1 C to 3 C. (b) EIS spectra of S@Super P coin cells before and after cycling. -- Figure S23. High-loading cycling performances with sulfur loadings of 7.6 mg cm-2 at 0.5 C of S@Ni-MOF-1D electrodes. -- Figure S24. (a) Galvanostatic charge/discharge profiles of S@Ni-MOF-1D at various current rates with a high sulfur loading of 4.3 mg cm−2. (b) Rate capability of S@Ni-MOF-1D cathodes loaded with 4.3 mg cm−2 of sulfur at various C rates. -- Figure S25. (a) TGA curve of a S@Ni-MOF-1D composite with a higher sulfur loading. (b) Cycling stability and Coulombic efficiency of the S@Ni-MOF-1D cathode with a higher sulfur loading at 1 C for 250 cycles. -- Table S2 Summary of recent reports on MOF-based sulfur host cathodes for LSBs., ICN2 acknowledges the support from the Severo Ochoa Programme (MINECO, Grant no. SEV-2017-0706). IREC and ICN2 are both funded by the CERCA Programme/Generalitat de Catalunya., Peer reviewed

Table S1: Predictive regression models describing the relationships between the nutritional and bioactive attributes of extrudates with corn-sprouted pseudocereal flour blends., Peer reviewed

Figure S1. Time sweeps at 1 Hz and at 20 °C of a commercial fatty preparation (CFP), a commercial butter (CB) and two formulated margarines (FM8 and FM9). Shear stress (σ) was chosen in the LVR (20 Pa for CB and 200 Pa for CFP, FM8 and FM9). G′, elastic modulus; G″, viscous modulus. Figure S2. Frequency sweeps carried out at 1 Hz and at 20 °C to determine the mechanical spectra of a commercial fatty preparation (CFP), a commercial butter (CB) and different formulated margarines (FM1, FM2, FM4 and FM7). G′, elastic modulus; G″, viscous modulus. Figure S3. Thermograms obtained by DSC; (a) cooling crystallization profile of palm stearin (PS), a commercial fatty preparation (CFP) and one formulated margarine (FM7); (b) cooling crystallization and heating melting profiles of a commercial fatty preparation (CFP). Figure S4. Polarized light microscopy (PLM) images of a commercial fatty preparation (CFP), a commercial butter (CB) and different formulated margarines (FM2, FM4, FM5 and FM8)., Peer reviewed

Powerpoint document: Supplementary data 1. Word document: Supplementary data 2 and Supplementary data 3., Peer reviewed

7 pages. -- Supplementary data, containing plots of calculated diamond Seebeck thermopower, mobility and thermal conductivity compared to measured data, electron and phonon scattering rates, and thermoelectric power factor., Peer reviewed

Supplementary data to this article: Table S1. Pearson’s correlation coefficient between mineral content in Brazilian cheese and nutrient composition Table S2. Pearson’s correlation coefficient between mineral and fat content in Brazilian cheese and mineral availability. Table S3. Pearson’s correlation coefficient between furosine content (mg/100 g protein) and mineral availability., Peer reviewed

Supplementary data 1. Supplementary data 2: Supplementary Table S1. Validation values for the proposed models. Supplementary data 3: Supplementary Table S2. Concentration of major phenolic compounds identified in mango by products extracted by conventional and ultrasound assisted extraction. Supplementary data 4: Supplementary Table S3. Unidentified peaks spectrometric parameters., Peer reviewed

16 pages. -- This file includes: Figure S1. Prisma. -- Table S1. Details of the 52 studies used in the meta-analysis. Phylogenetic meta-analysis. -- Table S2. Crop species included in the phylogeny. -- Figure S2. Phylogeny of the 30 crops studied. -- Figure S3. Overall and individual model-adjusted estimations of pollination limitation., Supporting information associated with the main manuscript., Peer reviewed

2 pages. -- File includes: evaluation metrics, Peer reviewed

Supplementary data to this article: Multimedia component 1. (PDF) Multimedia component 2., Peer reviewed