BUSCADOR RECOLECTA

The raw data are organized in folders based on the kind of device presented in the paper. The Juppyter notebooks contain the code for analyzing and plotting the data, there is one notebook for each figure of the papaer and supplementary. The scripts used to import the datasets of different kinds are contained in util_scripts, along with some other useful functions for plotting and formatting., Fig2 - SNS.ipynb, Peer reviewed

[Description of methods used for collection/generation of data] In order to characterize the assemblage of plant below-ground associated fungi in 42 Mediterranean woody species, we collate our own data, from molecular identification of AM (see Garrido et al. 2023 for a complete description of the methods) and EcM fungi (see Prieto et al. 2022 for a complete description of the methods), with bibliographic information containing molecular data for root-associated fungi, for the studied plant species, from MaarjAM database for AM (Opik et al. 2010) and from bibliographic review for EcM fungi. The bibliographic review for EcM molecular data was performed with the following terms: "Genus_species" AND "Ectomyco*" OR "EcM" AND "OTU" OR "VT"., Our aim was to register and characterize, through collating our own data with those from bibliographic reviews of published databases including root-associated fungi molecular data, the mycobiome of Mediterranean woody plant species across Europe and North Africa. Here, we reported a total of 439 fungus taxa associated with the roots of 42 woody species, involving 3086 plant belowground-fungus interactions., This work was funded (1) by Proyecto FEDER SUMHAL-Sustainability for Mediterranean Hospost in Andalusia integrating LifeWatch ERIC [Work Package 5. Task 5.1.2. Development of the data standard. Repository development.] (LifeWatch ERIC – FEDER, POPE 2014-2020; Ministerio de Ciencia e Innovación, Spain); (2) Proyecto COEXMED I: Coexistence of woody plants in Mediterranena forests: intransitive interactions and negative density dependence in recruitment dynamics (CGL2012-36776, FEDER y Ministerio de Economia y Competitividad, Spain); (3) Proyecto COEXMED II: Especificidad de las interacciones adulto-juvenil durante el reclutamiento de plantas leñosas: complementariedad de caracteres funcionales e interacciones plant-antagonista (CGL2015-69118-C2-1-P, FEDER y Ministerio de Economia y Competitividad, Spain); (4) Proyecto REPNETS-Redes de reemplazamiento en bosques: variación ecogeográfica e influencia de las comunidades de hongos de la filosfera y de las interacciones planta-suelo (PGC2018-100966-B-I00, FEDER - Agencia Estatal de Investigación, Ministerio de Ciencia e Innovación, Spain); (5) CSIC is acknowledged for supporting Open Access publication., Plant_below-ground_fungi_interactions_database_for_42_Mediterranean_woody_species_across_Europe_and_North_Africa.csv [shows root-associated fungus interactions, determined by molecular techniques, for 42 Mediterranean woody species] Plant_taxonomic_info.csv [shows the list of woody plant species with their taxonomic adscription Class/Order/Family/Genus] Metadata.csv [records information about the meaning of columns in 'Plant_below-ground_fungi_interactions_database_for_42_Mediterranean_woody_species_across_Europe_and_North_Africa.csv' and 'Plant_taxonomic_info.csv ' files], Peer reviewed

3 pages. -- Fig S1. A) TG-DSC curves of pure PAN and PAN-Ni/Co(Acac)2 nanofibers heated in atmosphere of air. B) TG-DSC curves of ox-PAN and ox-PAN-Ni/Co(Acac)2 nanofibers heated in nitrogen. -- Fig S2. A) BFTEM image of eCNF/CNT/NiCoNP nanocomposite. B) and C) HRTEM images of NiCo nanoparticles embedded in the carbon shells. -- Fig S3. a) HAADF-STEM image and EDS elemental distribution on the surface of eCNF/CNT/NiCoNP nanocomposite (sample HN-700-10), b) The HRTEM image of NiCo nanoparticle and corresponding interplanar distance diagram. -- Fig S4. Scan-rate dependent cyclic voltammograms of selected electrocatalytic materials in iodide electrolyte. A) Pt disc electrode; B) Neat eCNF; C) HN700-10; D) HN850-7; E) HN850-10; F) HN850-30. -- Fig S5. Randles–Ševčík plots of triiodide ions reduction at nanocomposites synthetized at various A) temperatures, and B) durations of CCVD. -- Fig S6. Charge transfer resistance at counter electrode-electrolyte interface of DSSC as function of applied voltage., Peer reviewed

6 pages. -- S1. Transversal electric field distribution for the SLR at 1.57 eV. -- S2. Simulated electric field and charge distributions for a threesome of slits. -- S3. Simulated electric field and charge distributions for the simplest local dark mode of the inverted honeycomb lattice. -- S4. Profiles of the EELS signal and the simulated electric field along the slits for the antiferroelectric dark modes. -- S5. Array of the magnetic dipoles over the structure used to simulate antiferroelectric dark modes., Plasmonic lattice nanostructures are of technological interest because of their capacity to manipulate light below the diffraction limit. Here, we present a detailed study of dark and bright modes in the visible and near-infrared energy regime of an inverted plasmonic honeycomb lattice by a combination of Au+ focused ion beam lithography with nanometric resolution, optical and electron spectroscopy, and finite-difference time-domain simulations. The lattice consists of slits carved in a gold thin film, exhibiting hotspots and a set of bright and dark modes. We proposed that some of the dark modes detected by electron energy-loss spectroscopy are caused by antiferroelectric arrangements of the slit polarizations with two times the size of the hexagonal unit cell. The plasmonic resonances take place within the 0.5–2 eV energy range, indicating that they could be suitable for a synergistic coupling with excitons in two-dimensional transition metal dichalcogenides materials or for designing nanoscale sensing platforms based on near-field enhancement over a metallic surface., Peer reviewed

14 pages. -- Table of Contents: Experiment Procedures. -- Characterization. -- Photocatalytic H2 Evolution Test. -- Electrochemical characterizations. -- Supplementary Figures., Peer reviewed

26 pages. -- Figure S1. Photo of the fluidic sensing system used in our study. -- Figure S2: Raman spectrum of GSH nanosheet. --Figure S3. Optimization of different supporting electrolytes and concentrations. -- Figure S4. Optimization of different volumes of GSH supernatant drop-casted on SPCEs and deposition potential. -- Table S1 The detailed data in optimization of different deposition potentials. Fgure S5. Optimization of flow time and flow rate. -- Figure S6. The individual HM ions detection. -- Figure S7. Cyclic voltammetry and electrochemical impedance spectroscopy of Bare and GSH-SPCE. -- Table S2. The detailed fitting results in electrochemical impedance spectroscopy. -- Figure S8. The comparison between individual measurements and simultaneous measurements on bare SPCE in our previous study. -- Figure S9. The absence of peak B in individual detection of 80 ppb Pb. -- Table S3. The summary of the obtained sensitivity (calibration slope), Y-intercept and R2 in all comparative experiments in this study. -- Table S4. The LODs of GSH-SPCE and bare SPCE towards Cd, Pb and Cu in the simultaneous detection. -- Figure S10. The data of sensing signals in repeatability study. -- Table S5. Summary of reusable times and repeatability in other studies using Bi-based electrodes and non-covalently functionalized graphene derivatives/composites. -- Table S6. The data of sensitivities in reproducibility study and Student´s T-test. -- Figure S11. The estimated concentration of GSH, GA and GO is characterized by UV-Vis. -- Table S7. Typical hard and soft acids and bases example. -- Figure S12. The detailed data in the interference study. -- Figure S13. The sensing performance of GSH-SPCE in spiked tap water. -- 23 Table S8 The investigation of the accuracy of GSH-SPCE in spiked tap water. -- Table S9. Comparison with other studies in the literature., Heavy metal pollutants are of great concern to environmental monitoring due to their potent toxicity. Electrochemical detection, one of the main techniques, is hindered by the mutual interferences of various heavy metal ions in practical use. In particular, the sensitivity of carbon electrodes to Cd2+ ions (one of the most toxic heavy metals) is often overshadowed by some heavy metals (e.g. Pb2+ and Cu2+). To mitigate interference, metallic particles/films (e.g. Hg, Au, Bi, and Sn) typically need to be embedded in the carbon electrodes. However, these additional metallic materials may face issues of secondary pollution and unsustainability. In this study, a metal-free and sustainable nanomaterial, namely cysteamine covalently functionalized graphene (GSH), was found to lead to a 6-fold boost in the Cd2+ sensitivity of the screen-printed carbon electrode (SPCE), while the sensitivities to Pb2+ and Cu2+ were not influenced in simultaneous detection. The selective enhancement could be attributed to the grafted thiols on GSH sheets with good affinity to Cd2+ ions based on Pearson's hard and soft acid and base principle. More intriguingly, the GSH-modified SPCE (GSH-SPCE) featured high reusability with extended cycling times (23 times), surpassing the state-of-art SPCEs modified by non-covalently functionalized graphene derivatives. Last, the GSH-SPCE was validated in tap water., Peer reviewed

32 pages. -- Experimental details. -- Computational details. -- Calculating binding energies. -- Calculating ORR activity, Electrolyte effects play an important role in the activity of the oxygen reduction reaction (ORR) of Pt-based electrodes. Herein, we combine a computational model and rotating disk electrode measurements to investigate the effects from phosphate anion poisoning for the ORR on well-defined extended Pt surfaces. We construct a model including the poisoning effect from phosphate species on Pt(111) and Cu/Pt(111) based on density functional theory simulations. By varying the subsurface Cu content of the Cu/Pt(111) alloy, we tune the *OH binding energies on the surface by means of ligand effects, and as a result, we tune the ORR activity. We have investigated the effect of adsorbed phosphate species at low overpotentials when tuning *OH binding energies. Our results display a direct scaling relationship between adsorbed *OH and phosphate species. From the model, we observe how the three-fold binding sites of phosphate anions limit the packing of poisoning phosphate on the surface, thus allowing for *OH adsorption even when poisoned. Our work shows that, regardless of surface site blockage from phosphate, the trend in the catalytic oxygen reduction activity is predominantly governed by the *OH binding., Peer reviewed

14 pages. -- PDF includes: 1 Methods. -- 1.1 Synthesis of the molecular precursors. -- 1.2 Sample preparation and on-surface synthesis. -- 1.3 Experimental details on the imaging method. -- 1.4 Ab-initio Calculations and quantum electron transport simulations. -- 2 Analysis of interpolymer distance. -- 3 Electronic properties of Ph-7-13-AGNR. -- 4 Surface-induced planarization of the peripheral phenyl ring in isolated ribbons., Recent advances on surface-assisted synthesis have demonstrated that arrays of nanometer wide graphene nanoribbons can be laterally coupled with atomic precision to give rise to a highly anisotropic nanoporous graphene structure. Electronically, this graphene nanoarchitecture can be conceived as a set of weakly coupled semiconducting 1D nanochannels with electron propagation characterized by substantial interchannel quantum interferences. Here, we report the synthesis of a new nanoporous graphene structure where the interribbon electronic coupling can be controlled by the different degrees of freedom provided by phenylene bridges that couple the conducting channels. This versatility arises from the multiplicity of phenylene cross-coupling configurations, which provides a robust chemical knob, and from the interphenyl twist angle that acts as a fine-tunable knob. The twist angle is significantly altered by the interaction with the substrate, as confirmed by a combined bond-resolved scanning tunneling microscopy (STM) and ab initio analysis, and should accordingly be addressable by other external stimuli. Electron propagation simulations demonstrate the capability of either switching on/off or modulating the interribbon coupling by the corresponding use of the chemical or the conformational knob. Molecular bridges therefore emerge as efficient tools to engineer quantum transport and anisotropy in carbon-based 2D nanoarchitectures., Peer reviewed

17 pages. -- 1. Experimental Section. -- 2. Supplementary Table S1-S2 and Figs. S1-S17. -- 3. References, Peer reviewed

Description of methods used for collection-generation of data: Refractive index measurements: data was obtained using an Abbe refractometer NAR-1T. The temperature was controled with a recirculating thermobath system. 1-bromonaphtalene was used as inmersion oil for PVA film. Transmittance measurements: data was obtained using a Jasco U-770 or an Agilent Cary 60 spectrophotometers. The temperature of the samples was controlled with a Peltier thermostated cell holder, with an external air heating gun (output air temperature of 55 °C), or with a custom-made holder (Sapphire 360) in which the sample of interest was kept between two sapphire windows attached to two cupper sheets, which were connected to a temperature controller. Differential scanning calorimetry measurements: data was obtained using a TA-instruments Q20. A temperature ramp rate of 10 °C min-1 was used for all the samples. Sample irradiation: Irradiation was performed with: (a) a cw laser (irradiation wavelength 830 nm), whose power was modulated using different neutral density filtersand measured with a potentiometer; (b) a solar simulator (100 mW cm-2) placed at 23 cm from the tested material, whose irradiation power was measured with a potenciometer; or (c) sunlight. Temperature measurements on samples: Temperatures were measured with: (a) a thermocouple; or (b)a thermal IR probe. Voltage application to samples: The voltage was applied by means of a power supplier and both the voltage and the current were displaid in the power supplier screen. Electron microscopy data: TEM images were acquired with a TEM JEM-1400 (120 kV) microscope. SEM images were acquired with a FEI Quanta 650 ESEM microscope applying a 5 kV voltage. Size histograms were obtained from the microscopy images using ImageJ software. Stress-strain curves: The tensile test of the films was conducted by means of an Instron 3366 instrument at a speed of 25 mm min-1 and the specimens used had a thickness of 0.2 mm and a width of 15 mm., The dataset shows the experimental data provided in the main text and supporting information of the article "Multistimuli-responsive smart windows based on paraffin-polymer composites": thermal variation of refractive index, thermal and time variation of transmission spectra, electron microscopy images, differential scanning calorymetry thermograms, variation of transmission spectra with light irradiation and voltage application, temperature variation into house models upon sunlight irradiation., Funding sources: Funding agency: MINECO/FEDER. Project number: (RTI2018-098027-B-C21, PID2019-106171RB-I00 and PDC2022-133368-I00). Funding agency: Generalitat de Catalunya. Project number: 2017 SGR00465 and 2021 PROD 00190, Fig 2 Folder, Fig 3 folder, Fig 5 folder, Fig 6 folder, Fig 7 folder, Supporting information folder, Peer reviewed