Digital.CSIC. Repositorio Institucional del CSIC

oai:digital.csic.es:10261/337445

19 pages. -- List of Schemes: S1. AbPPO4-loaded SBA-15 materials and structures of the phenolic substrates used for catalysis. -- S2. Reaction mechanism of the oxidation of phenolic compounds by AbPPO4. List of figures: S1. SDS-PAGE (8–15% acrylamide) of the expression of AbPPO4 by Escherichia coli BL21(DE3). -- S2. Characterization of the structured ordering and porosity of SBA-15 and SBA-15-NH2 by low-angle XRD, TEM and N2-physisorption. -- S3. Internal structure and outer dimensions of latent AbPPO4. -- S4. Mass loss and DSC profiles of SBA-15, SBA-15-NH2 and AbPPO4-loaded silica. -- S5. Solid-state 29Si CP/MAS NMR of SBA-15 and SBA-15-NH2. -- S6. UV/Vis spectra of the supernatants obtained after AbPPO4 loading. -- S7. N2-sorption isotherms and NLDFT pore size distribution of adsorbed AbPPO4 on mesoporous silica. -- S8. Low-angle XRD patterns of the different tyrosinase-loaded samples SBA-15-NH2-Tyr. -- S9. Leaching test performed for SBA-15-Tyr during the catalytic oxidation of L-tyrosine. -- S10. Oxidation of L-tyrosine by free AbPPO4, SBA-15-Tyr and SBA-15-NH2-Tyr followed by 1H-NMR. -- S11. UV/Vis spectra of the supernatants obtained after 20 min adsorption of oxidized phenols on mesoporous silica. -- S12. Influence of SDS concentration on dopachrome production in the reaction of L-tyrosine with SBA-15-Tyr. -- S13. ATR-FTIR spectra of AbPPO4 loaded on mesoporous silica. List of tables: S1. Assignment of the signals in the solid-state 29Si CP/MAS NMR spectra of pure and functionalized silica. -- S2. Porosity and textural properties obtained from the N2-physisorption analysis. -- S3. Assignment of the signals of the ATR-FTIR spectra of SBA-15-Tyr and SBA-15-NH2-Tyr measured before and after their reaction with tyrosine., Peer reviewed