Resultados de investigación

[Description of methods used for collection/generation of data] Data acquired with a high-kinetic-energy Scienta EW 4000 hemispherical analyser installed on the HAXPES endstation of the GALAXIES beamline of the French national synchrotron facility SOLEIL (France) [Methods for processing the data] CasaXPS software., Original raw data (uncorrected energies) of HAXPES spectra obtained at the HAXPES endstation of the GALAXIES beamline at SOLEIL synchrotron facility (France). Each spectrum is displayed in a two-column format, kinetic energy (X) vs. HAXPES intensity (Y). Photon energies are indicated for each figure., [FIGURE 5] HAXPES raw data of the Au 4f region in kinetic energy (X) vs. intensity (Y) columns of a 40 nm Au film (au_film_40nm), a dispersion of Au nanoparticles on a 25 nm-thick membrane in air (au_np_cell16), a dispersion of Au nanoparticles in MilliQ water (au_np_cell17) and a Au film treated with oxygen plasma and measured with 1486.6 eV photons (au_film_O2_plasma, data from DOI: 10.1021/acs.accounts.8b00241). Photon energy = 5 keV., [FIGURE 6] HAXPES raw and normalized (norm) data of the (a) N 1s, (b) O 1s, (c) C 1s and (d) F 1s lines obtained with 7 keV photons and using 20 nm thick membranes. Liquid cells filled with: air (S2), vacuum (S4), with air and with a ca 5 nm-thick amorphous carbon coating deposited in the inner part of the membrane (S7) and with 60 ml of the LP57 electrolyte (1 M LiPF6 in EC:EMC 3:7) and with the ca 5 nm-thick carbon coating (S6). The formulas used for normalization (heights normalized to their corresponding maxima) are displayed in the corresponding Y columns. In Fig. 6(d) a least-squares fit using the CasaXPS software after a Shirley-type background subtraction using a combination of Gaussian (70%) and Lorentzian (30%) functions under the constraint of identical full width at half-maximum (FWHM) for all components is shown. Raw and corrected kinetic energies are given., [FIGURE 7] HAXPES raw data of the (a) Na 1s region of a 3.5 M NaCl aqueous solution and (b) Cs 3d and (c) Cs 4d lines of a 2.6 M aqueous solution of CsCl obtained with 7 keV photons and using 15 nm membranes., [FIGURE S1] (Top) simulation of the inelastic mean free path (nm) as a function of the kinetic energy in silicon nitride using the TPP-2M model and assuming a 3.44 gr cm-3 density for silicon nitride. (Bottom) Simulated HAXPES spectra assuming a 15 nm thick silicon nitride layer on a CsCl substrate in the 3-10 keV photon energy range., European Union’s Horizon 2020 research and innovation programme, under grant agreement No. 101007417 NFFA-Europe Pilot. Spanish Ministry of Science and Innovation (MCIN) under contract No. PID2021-124568NB-I00. ICN2 is funded by the CERCA program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa Centres of Excellence programme, grant CEX2021-001214-S, funded by MCIN/AEI. Support through the Marıa de Maeztu grant CEX2023-001397-M funded by MICIU/AEI is acknowledged. Generalitat de Catalunya through the 2021-SGR-00644 project. European Union’s Horizon 2020 research and innovation programme under grant agreement No. 957189., With funding from the Spanish government through the "Severo Ochoa Centre of Excellence" accreditation (CEX2021-001214-S)., With funding from the Spanish government through the "Severo Ochoa Centre of Excellence" accreditation (CEX2023-001397-M)., File List: Fig_5.xls; Fig_6a.xls, Fig_6b.xls, Fig_6c.xls, Fig_6d.xls, Fig_7.xls, Fig_S1.xls, Peer reviewed

XRD patterns of bulk Sr2CoO3–CoO2 along with schematic crystal structure; TEM images of a partially rolled SrCoO2–CoO2; TEM and HR-STEM ADF micrographs of SrCoO2–CoO2 nanotubes synthesized at high concentration of NaOH; total density of states (DOS) for the (SrCoO2)–(CoO2)2 supercell and its projection on to the SrCoO2 and CoO2 layers; comparison of the total DOS for the (SrCoO2)–(CoO2)2 supercell with that for the (CaCoO2)–(CoO2)2 supercell., Peer reviewed

Structural parameters derived from Rietveld analysis of the XRD pattern of Y2Ni7; results from EPMA for Y2Ni7; XRD patterns of Gd2Ni7 before and after PCT measurement at maximal pressure; crystallographic information (cif) files for the three deuterides structures determined by Rietveld refinement of PND data., Peer reviewed

Further fabrication parameters; XRD, TG, SEM, and EDS analyses on the green and sintered HF supports; ZIF powders and ZIF-9-III@Ni HF membrane; lattice parameter data calculated under changes in temperature and the consequent TECs calculated for ZIF powders; and equations used; and comparison of the H2/CO2 separation performance with other HF membranes reported in the literature., Peer reviewed

Experimental details, TGA, XRD, FTIR, particle size, TEM, FFT characterizations., Peer reviewed

Additional nanoparticle characterization including UV–vis–NIR, SERS spectroscopies, and TEM., Peer reviewed

Synthetic and crystallographic details, CShMs, and various structural figures and tables., Peer reviewed

Experimental and theoretical details and 1H NMR and 13C NMR spectra., Peer reviewed

1) TEM images of TEG-SPIONs samples synthesized by using different heating rate to heat from 25 to 280 °C and by using different aging at 180 at 280 °C. 2) TEM micrographs of sample aliquots extracted from the reaction at different reaction time., Peer reviewed

Table S1: Parameters modified in order to optimize the synthesis conditions to obtain highly homogeneous and monodisperse particle size distributions. Figure S1: Fluorescein release after immersion in simulated gastric fluid and simulated intestinal fluid. Figure S2: Morphology of Escherichia coli S17 and Lactobacillus acidophilus. Figure S3: Thermogravimetric analysis data showing weight loss of the enteric polymers and bacteria (Lactobacillus acidophilus). Figure S4: Free bacteria viability test results showing bacterial cell counts of Escherichia coli and Lactobacillus acidophilus after immersing them in simulated gastric and/or intestinal fluids for 2 h and 24 h, respectively. Figure S5: Bacteria viability test results of the long-term stability study of lyophilized Eudraguard and Eudragit-coated bacteria after different times showing bacterial cell counts of Escherichia coli and Lactobacillus acidophilus after immersing them in simulated gastric and intestinal fluids., Peer reviewed