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TENSIONES MECANICAS EN COMPONENTES LAMINARES DE IONES LITIO: LA MURALLA A FRANQUEAR PARA EL USO DE BATERIAS DE LI EN APLICACIONES INTENSIVAS

PCI2019-103604

Nombre agencia financiadora Agencia Estatal de Investigación
Acrónimo agencia financiadora AEI
Programa Programa Estatal de I+D+i Orientada a los Retos de la Sociedad
Subprograma Programación Conjunta Internacional
Convocatoria Proyectos I+D
Año convocatoria 2019
Unidad de gestión Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020
Centro beneficiario AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS (CSIC)
Identificador persistente http://dx.doi.org/10.13039/501100011033

Publicaciones

Resultados totales (Incluyendo duplicados): 1
Encontrada(s) 1 página(s)

Imaging phase segregation in nanoscale LixCoO2 single particles

Docta Complutense
  • Fuller, Elliot J
  • Ashby, David S
  • Polop, Celia
  • Salagre, Elena
  • Bhargava, Bhuvsmita
  • Song, Yueming
  • Vasco, Enrique
  • Sugar, Joshua D
  • Albertus, Paul
  • Mentes, Tevfik Onur
  • Locatelli, Andrea
  • Segovia, Pilar
  • González Barrio, Miguel Ángel
  • Mascaraque Susunaga, Arantzazu
  • Michel, Enrique G
  • Talin, A. Alec
Li xCoO2 (LCO) is a common battery cathode material that has recently emerged as a promising material for other applications including electrocatalysis(1, 2) and as electrochemical random access memory (ECRAM)(3). During charge-discharge cycling LCO exhibits pase transformations that are significantly complicated by electron correlation. While the bulk pase diagram for an ensemble of battery particles has been studied extensively, it remains unclear how these phases scale to nanometer dimensions and the effects of strain and diffusional anisotropy at the single particle scale. Understanding these effects is critical to modeling battery performance and for predicting the scalability and performance of electrocatalysts and ECRAM. Here we investigate isolated, epitaxial LiCoO2 islands grown by pulsed laser deposition (PLD). After electrochemical cycling of the islands, conductive atomic force microscopy (c-AFM) is used to image the spatial distribution of conductive and insulating phases. Above 20 nm island thicknesses, we observe a kinetically arrested state in which the phase boundary is perpendicular to the Li-planes; we propose a model and present image analysis results that show smaller LCO islands have a higher conductive fraction than larger area islands, and the overall conductive fraction is consistent with lithiation state. Thinner islands (14 nm), with a larger surface to volume ratio, are found to exhibit a striping pattern which suggests surface energy can dominate below a critical dimension. When increasing force is applied through the AFM tip to strain the LCO islands, significant shifts in current flow are observed, and underlying mechanisms for this behavior are discussed. The c-AFM images are compared with photoemission electron microscopy (PEEM) images which are used to acquire statistics across hundreds of particles. The results indicate that strain and morphology become more critical to electrochemical performance as particles approach nanometer dimensions.