BUSCADOR RECOLECTA

STM-ncAFM from IMDEA Nanociencia Institute and CATRIN under ultra-high vacuum conditions at 4K, acquired between 2018 and 03.2023, *.txt *.jpg *.docx files, *.WSxM files can be opened with Origin

-1H, 13C{1H}, and 31P{1H} NMR spectra of complexes 2–5 and crystal, measurement, and refinement data for the compounds studied by XRD (PDF). -Atomic coordinates for the DFT-optimized structures (XYZ)., Peer reviewed

Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic data Center, CCDC 1451708 for the complex. Copies of the data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html., Peer reviewed

-1H and 13C{1H} NMR spectra of L2, 3, and 7; 1H and 31P{1H} NMR spectra of the outcome of the reaction of 1 with 3; images and metric parameters of the DFT-optimized structures of 3, 4, 6, and 7; results of catalytic experiments; crystal, measurement, and refinement data for the compounds studied by XRD (PDF). -Atomic coordinates for the calculated structures (XYZ)., Peer reviewed

Figure S7. Supplementary material. Crystallographic data for the structural analyses were deposited with the Cambridge Crystallographic Data Center 1473715 for the complex., Peer reviewed

Supplementary data 1. Crystallographic data for the structural analysis have been deposited on the Cambridge Crystallographic data Center (CCDC 1514267), and copies of the data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html. Additional experimental details, structural characterization data (Projection along the a-axis showingthe polymeric an 1-D endless inorganic chain, projection of the structure of [C6H16N2O]2+ cation along the a-axis showing the chair conformation of piperazinium entities, contributions to the Hirshfeld surface area for C6H16N2OPbCl4 and model for the formation and recombination of the exciton in the title compound are given in Fig S1–S4 and selected bond distances and angles in [C6H16N2O]PbCl4 and surface composition (in atomic %) are given in Table S1 and S2.), Peer reviewed

Supplementary crystallographic data for this article in CIF format are available at the Electronic Supplementary Publication from Cambridge Crystallographic Data Centre (CCDC 1560010). This data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, from the Cambridge Crystallographic Data Centre, 12 Union Rood, Cambridge CB2 1EZ, UK (Fax: (international): +44 1223/336 033; e-mail: deposit@ ccdc.cam.ac.uk). Projection along the b-axis showing the organic-inorganic layers in the title compound crystal, relative contributions to the Hirshfeld surface areas for the various intermolecular contacts, are given in Fig S1-S2 and selected bond distances and angles in (C5H14N2)2[SnCl6]2·5H2O and Surface composition (in atomic %) are given in Table S1 and S2., Peer reviewed

Figure S1: UV-VIS spectra of the SERS substrates herein studied: Glass_ Ag, Glass_AuNPs, Glass_Ag_AuNPs, 1G_Ag_AuNPs, 3G_Ag_AuNPs; Figure S2: SERS spectra of 6 spots recorded on bottom and top of 1G_Ag_AuNPs sample upon exposure to 1.2 ppmV DMMP in gas phase., Peer reviewed

Climatic information recorded by the physician Francisco Fernández Navarrete in Granada (southern Spain) during the first third of the 18th century. Observations are included in the book “Cielo y suelo granadino” (Sky and soil in Granada), and consist of qualitative comments relating climatic conditions to illness and diseases from 1706 to 1730, as well as instrumental observations (using an “English barometer” and a “Florentine thermometer”) from December 1728 to February 1730.

New meteorological data from southern Spain corresponding to the period 1785-1830. Data sources are early newspapers and medical studies interested in the influence of environment conditions on health and illness. Data correspond to five cities in the area (Cádiz, Sevilla, Málaga, Granada, and Cartagena). Around 19.000 new meteorological observations (temperature, pressure, number of rainy days, wind direction, and qualitative statements on rainfall, wind force, cloudiness, fog, and storms) are recorded.